Program crashes when running it outside dev environment

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I use Visual C 2005 to develop my programs. One in particular is
crashing in very specific and hard to replicate situations, made worse
by the fact it only crashes when run -outside- the dev - as an exe,
not from the Debug option. If I try to launch the debug on the
crashing program, it'll close before the debugger opens. Any
suggestions as to how I should proceed? Thanks in advance.

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